There been some suspects that if both vray for SU and Thea for SU are installed there is change for a crash (maybe observers do not play well). Anyhow... about the crash, you really should post a detailed bug report at Thea forums (if you not already have done so); used software version (su, thea & vray..., os, hardware specks, gpu drivers and so) so that Tomasz can take a look on this.
http://www.thearender.com/forum/viewforum.php?f=82