You must uncheck "Use default value" first ...
ADD: OR.. you can hilight "[Default]" at the top of the list, and change the default to what you want most of your code to do with TAB characters.
Then change the specific few languages that you want to be different (ie: Python, Javascript, Java, HTML and CSS, all use 4 space tabs, instead of 2. Likely all the C language family as well. C, C++ and C#.)