On Mac's, .pngs automatically export with transparent backgrounds.
PC's don't, however. I believe there ways of doing it with either rendering plugins (twilight, podium, vray, etc), or perhaps just adjusting the colors and shadows of the model to white and black and re-exporting the animation frames, to come up with alpha frames for the entire animation.
I've not tried it on a film though, just on one frame photos.
Chris