hi tronik .
i got the same problem & i found that if U are gonig to change the materialls setting in SU (Like scaleing, rotating , Colors & ...) many time the chages dosen't apply to V-Ray. (and i think that it happend when You are useing one kind of matterials in to form like one brik with to scale in one file or with to colours)
I use this to remove it but i think there must be a beter way.
1 - i export the materaills to JPEG.
2 - do what i want to do with that in Photoshop and save as JPEG
3 - Import image as texture and use it on somewhere (every where i want)
4 - save that to .skp file and use it.